Oxidation of sulphide Minerals in Hydrometallurgical Systems.

Acid leaching and dissolution of major sulphide ore minerals: processes and galvanic effects in complex systems

The kinetics and mechanisms of dissolution of the major base metal sulphide minerals, pyrite, chalcopyrite, galena and sphalerite in acidic (chloride) media have been investigated. Minerals were ground in air, then dissolved in air-equilibrated solutions at pH 2.5, while monitoring the redox potential. Solution samples were analysed by ICP-AES and HPLC, and surfaces of residual sulphides analys...

Energy conservation in Thiobacillus neapolitanus C6 sulphide and sulphite oxidation.

Diagenetic formation of ferrimagnetic iron sulphide minerals in rapidly deposited marine sediments, South Island, New Zealand

Detailed magnetostratigraphic studies of Late Neogene siliciclastic sediments of the Awatere Group, South Island, New Zealand (41°45'S, 174°05'E) have revealed a wide range of palaeomagnetic behaviour. Examination of rock magnetic properties was undertaken using conventional palaeomagnetic techniques and thermomagnetic, X-ray diffraction and electron microprobe analyses. These analyses indicate...

Nitrite and nitrate as electron acceptors for biological sulphide oxidation.

Autotrophic denitrification with sulphide using nitrate (R1) and nitrite (R2) as electron acceptor was investigated at bench scale. Different solids retention times (SRT) (5 and 20 d) have been tested in R1 while R2 was operated at SRT=13 d. The results indicated that the process allows complete sulphide removal to be achieved in all tested conditions. Tested sulphide loads were estimated from ...

Biogenic catalysis in sulphide minerals' weathering processes and acid mine drainage genesis.

Bioleaching and biogenesis are the main outputs from a large group of environmental processes participating in the natural material cycle, used in raw materials processing. Bio-oxidation reactions are the main basis for bioleaching procedures, often participating in parallel leaching processes. During the leaching processes of polycomponent sulphide substrates, the factor of process selection a...